Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches.
نویسنده
چکیده
Design of rotatory molecular switches based on extremely stable sandwich organometallic complexes ferrocene and bis(dicarbollide) complexes of transition metals is reviewed. The "on"-"off" switching in these systems can be controlled by various external stimuli such as change of the solution pH, interactions with coordinating species or redox reactions involving the central atom or substituents in the ligands.
منابع مشابه
Design of Biosensors Based Transition-Metal Dichalcogenide for DNA-base Detection: A First-Principles Density Functional Theory Study
The main function purpose of nanobiosensors is to sense a biologically specific material and the kind of sensing platform and doping engineering has been an emerging topic and plays an important role in monolayer molybdenum disulfide (mMoS2). In this paper, we theoretically reveal the electronic structures of mMoS2 doped by 3d transition metals. Furthermore, adsorption of nucleic acid [Adenine ...
متن کاملFerrocenylalkynes as ligands in transition metal complexes
Several ferrocenylalkynes have been prepared and their reaction with dicobalt octacarbonyl led to the formation of [Co2(CO)6(μ-η 2 : η-ethynylferrocene)] 1, [Co2(CO)6(μ-η 2 : η-1,4-bis(ferrocenyl)butadiyne)] 2, [(Co2(CO)6)2(μ-η : η,μ-η : η-1,4-bis(ferrocenyl)butadiyne)] 3, [Co2(CO)6(μ-η 2 : η-1-ferrocenylethynyl-2-hydro-1,2-dihydro[60]fullerene)] 4, [Co2(CO)6(μ-η 2 : η-1,1’-bis(phenylethynyl)fe...
متن کاملDissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...
متن کاملRecent Studies in Metal-cyclopentadienyl and Metal-arene Chemistry
The formation, chemical reactivity, and spectral properties of a variety of new ,r-bonded and G-bonded organic derivatives of the transition metals are described. The Effective Atomic Number (E.A.N.) Rule predicts the existence of an isoelectronic series of mixed 'sandwich' complexes which contain a cyclo-pentadienyl ring and carbocyclic rings of varying sizes. Bis(it-cyclopenta-dienyl)iron or ...
متن کاملAromatic amine N-oxide organometallic compounds: searching for prospective agents against infectious diseases.
In search of prospective agents against infectious diseases, 1,1'-bis(diphenylphosphino)ferrocene pyridine-2-thiolato-1-oxide M(ii) hexafluorophosphate compounds [M(mpo)(dppf)](PF6), where M = palladium or platinum, were synthesized and fully characterized in the solid state and in solution using experimental and DFT computational techniques. The compounds are isomorphous and the M(ii) transiti...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Molecules
دوره 22 12 شماره
صفحات -
تاریخ انتشار 2017